Tecnologia em Metalurgia, Materiais e Mineração
http://www.tmm.periodikos.com.br/article/doi/10.4322/2176-1523.20263350
Tecnologia em Metalurgia, Materiais e Mineração
Artigo Original

Nitrogen dynamics in steels produced in electric arc furnace and the challenges for the future

Rubia Teodoro Silva, Ismael Vemdrame Flores

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Abstract

The control of nitrogen content in steels produced via electric arc furnace (EAF) is one of the main metallurgical challenges faced by modern steelmaking, particularly considering the advancement of more sustainable and flexible production routes. This paper presents a technical review of the thermodynamic and kinetic mechanisms involved in nitrogen absorption in liquid steel, detailing the factors that influence its solubility, the incorporation pathways of the element, and the main methods used for its industrial control. The challenges of decarbonization are also discussed, with an emphasis on the implications of the transition to low-carbon technologies, such as hydrogen-based direct reduced iron (H-DRI), and their impact on the dynamics of nitrogen removal. By integrating fundamental knowledge with current operational approaches, this study aims to contribute to the improvement of EAF-based steelmaking processes focused on the production of high-quality steels.

Keywords

Electric Arc Furnace (EAF); Nitrogen control; Thermodynamics and kinetics; Decarbonization.

Referências

1 Madias J. Electric furnace steelmaking. In: Seetharaman, S, editor. Treatise on process metallurgy. USA: Elsevier; 2014. Vol. 3, p. 271-300.

2 World Steel Association. Annual Steel Data. Brussels: World Steel Association; 2024.

3 Kildahl H, Wang L, Tong L, Ding Y. Cost effective decarbonisation of blast furnace – basic oxygen furnace steel production through thermochemical sector coupling. Journal of Cleaner Production. 2023;389:135963. https://doi. org/10.1016/j.jclepro.2023.135963.

4 Madias J. Electric Arc Furnace. In: Cavaliere P, editor. Ironmaking and steelmaking processes: greenhouse emissions, control, and reduction. Cham: Springer; 2016.

5 Brooks G, Irons G, Anghelina D. New approach to nitrogen control in EAF steelmaking. In: High Temperature Processing Symposium; 2012; Australia. Australia: Swinburne University of Technology; 2012. https://doi. org/10.25916/sut.26290165.v1.

6 Turkdogan ET. Fundamentals of steelmaking. London: The Institute of Materials; 1996.

7 Zhang F, Li J, Liu W, Jiao A. The thermodynamics and kinetics of a nitrogen reaction in an electric arc furnace smelting process. Materials (Basel). 2023;16(1):33. PMid:36614372.

8 Zhan D, Wang J, Huang L, Zhang H. Effect of slag compositions on change behavior of nitrogen in molten steel. Metals. 2022;12(5):846. https://doi.org/10.3390/met12050846.

9 Irons GA, Anghelina D, Brooks GA. Nitrogen control in EAF steelmaking by DRI fines injection. Washington: American Iron and Steel Institute, Department Energy; 2004

10 Trotter D, Varcoe D, Reeves R, Anderson SH. Use of HBI and DRI for nitrogen control in steel products [Internet]. 2002 [cited 2025 Oct 24]. Available at: https://www.researchgate.net/publication/265107012

11 Pal J. Thermodynamic analysis of nitrogen removal in EAF by DRI fines injection. Ironmaking & Steelmaking. 2006;33(6):465-470. https://doi.org/10.1179/174328106X149824.

12 Wei G, Zhu R, Dong K, Li Z, Yang L, Wu X. Influence of bottom-blowing gas species on the nitrogen content in molten steel during the EAF steelmaking process. Ironmaking & Steelmaking. 2017;45(9):839-846. https://doi.org/1 0.1080/03019233.2017.1410949.

13 Wei G, Zhu R, Wu X, Dong K, Yang L, Liu R. Technological innovations of carbon dioxide injection in EAF-LF steelmaking. JOM Minerals, Metals and Materials Society. 2018;70:969-976. https://doi.org/10.1007/s11837-018- 2814-3.

14. Wei G, Zhu R, Wang Y, Wu X, Dong K. Technological innovations of electric arc furnace bottom-blowing in China. Journal of Iron and Steel Research International. 2019;26:909-916.

15 Costa e Silva A. Refino de aços: fundamentos e aplicações. São Paulo: Blucher; 2023. 440 p

16 Pilliod CF. Variables affecting the nitrogen content of carbon and low alloy acid electric arc furnace steels. In: Proceedings of the 46th Electric Furnace Conference; 1988; Pittsburgh (USA). Pittsburgh (USA): The Iron and Steel Society; 1988. p. 107-110.

17 Dutta SK, Lele AB. Production of Quality (Low Nitrogen) Steels by using Sponge Iron in EAF. Iron and Steel Review. 2011 [cited 2025 Oct 24];55(3). Available at: https://www.researchgate.net/publication/310492498

18 Erwee MW, Pistorius PC. Nitrogen in SL/RN direct reduced iron: origin and effect on nitrogen control in EAF steelmaking. Ironmaking & Steelmaking. 2012;39(5):336-341. https://doi.org/10.1179/1743281211Y.0000000076.

19 Derda W, Siwka J, Nowosielski CZ. Controlling of the nitrogen content during EAF-technology and continuous casting of steel. Archives of Metallurgy and Materials. 2008;53(2):523-529.

20 Pfeiffer A, Ernst D, Zheng H, Wimmer G, Schenk J. The behavior of direct reduced iron in the electric arc furnace hotspot. Metals. 2023;13(5):978. https://doi.org/10.3390/met13050978.

21 Pfeiffer A, Wimmer G, Schenk J. Investigations on the Interaction Behavior between Direct Reduced Iron and Various Melts. Materials (Basel). 2022;15(16):5691. https://doi.org/10.3390/ma15165691. PMid:36013836.

22 Pistorius PC. Steelmaking decarbonization options with current technology. Metallurgical and Materials Transactions. B, Process Metallurgy and Materials Processing Science. 2022;53(3):1335-1338. https://doi. org/10.1007/s11663-022-02463-z.


Submetido em:
24/10/2025

Aceito em:
15/01/2026

699752fda953953e735fb568 tmm Articles
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